The James Research Group

27. Nucleophilic Amination of Aryl Halides with an Azanide Surrogate

B. D. Cooper, T. D. Harris, E. R. X. Lim, K. A. Hooper, G. F. S. Whitehead, J. R. Carney, M. J. James*

26. Computational Design of Bidentate Hypervalent Iodine Catalysts in Halogen Bond-Mediated Organocatalysis

J. O'Brien, N. Melnyk, R. Shing Lee, M. J. James, C. Trujillo*

25. Computational Methods for Investigating Organic Radical Species

T. Renningholtz, E. R. X. Lim, M. J. James*, C. Trujillo*

◾  Invited contribution to a themed collection on Computational Organic Chemistry

24. Denitrative Sulfonylation of Nitroarenes with Sodium Sulfinates

J. Da Luz , M. Čierna , B. D. Cooper , T. D. Harris , E. R. X. Lim , J. R. Carney, M. J. James*

◾  Invited contribution to the special issue for the 10th Pacific Symposium on Radical Chemistry (PSRC-10)

23. Radical Dearomatising Spirocyclisation of Benzisoxazole-Tethered Ynones

N. Inprung, A. C. Whitwood, R. J. K. Taylor, M. J. James*, W. P. Unsworth*

◾  Invited contribution to the special collection on Radical Chemistry in Homogeneous Catalysis and Organic Synthesis

22. Denitrative Hydroxylation of Unactivated Nitroarenes

L. Duff^†, H. Meakin^†, A. Richardson^†, A. J. Greener, G. W. A. Smith, I. Ocaña, V. Chechik, M. J. James*

Preprint: ChemRvix 2022, DOI: 10.26434/chemrxiv-2022-9l5gq

◾  Highlighted in ChemistryViews and the Organic Chemistry Portal

21. Safe Handling of Air-Sensitive Organometallic Reagents Using Schlenk Line Techniques: Negishi Cross-Couplings for Trainee Graduate Students

M. J. James*, G. E. Clarke, C. Lee, I. J. S. Fairlamb*

20. Indole-ynones as Privileged Substrates for Radical Dearomatizing Spirocyclization Cascades

N. Inprung, H. E. Ho, J. A. Rossi-Ashton, R. G. Epton, A. C. Whitwood, J. M. Lynam, R. J. K. Taylor, M. J. James*, W. P. Unsworth*

19. Radical–Anion Coupling Through Reagent Design: Hydroxylation of Aryl Halides

A. J. Greener^†, P. Ubysz^†, W. Owens-Ward, G. Smith, I. Ocaña, A. C. Whitwood, V. Chechik, M. J. James*

Preprint: ChemRvix 2021, DOI: 10.33774/chemrxiv-2021-szmqs

◾  Highlighted in Synfacts

18. A Thiol-Mediated Three-Step Ring Expansion Cascade for the Conversion of Indoles into Functionalized Quinolines

N. Inprung, M. J. James*, R. J. K. Taylor*, W. P. Unsworth*

17. Visible-Light-Induced Intramolecular Charge Transfer in the Radical Spirocyclisation of Indole-Tethered Ynones

H. E. Ho, A. Pagano, J. A. Rossi-Ashton, J. R. Donald, R. G. Epton, J. C. Churchill, M. J. James, P. O'Brien, R. J. K. Taylor*, W. P. Unsworth*

16. Dynamic kinetic sensitization of β-dicarbonyl compounds – Access to medium-sized rings via a De Mayo-type ring expansion

T. O. Paulisch^†, L. A. Mai^†, F. Strieth-Kalthoff^†, M. J. James, C. Henkel, D. M. Guldi*, F. Glorius*

15. Visible-Light-Mediated Charge Transfer Enables C–C Bond Formation with Traceless Acceptor Groups

M. J. James, F. Strieth-Kalthoff, F. Sandfort, F. J. R. Klauck, F. Wagener, F. Glorius*

14. Visible-Light-Mediated Deaminative Three-Component Dicarbofunctionalization of Styrenes with Benzylic Radicals

F. J. R. Klauck, H. Yoon, M. J. James, M. Lautens*, F. Glorius*

13. Deaminative Borylation of Aliphatic Amines Enabled by Visible Light Excitation of an Electron-Donor-Acceptor Complex

F. Sandfort, F. Strieth-Kalthoff, F. J. R. Klauck, M. J. James, F. Glorius*

12. Energy Transfer Catalysis Mediated by Visible Light: Principles, Applications, Directions

F. Strieth-Kalthoff, M. J. James, M. Teders, L. Pitzer, F. Glorius*

11. Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

M. J. James, J. L. Schwarz, F. Strieth-Kalthoff, B. Wibbeling, F. Glorius*

10. Ag(I)-Catalyzed Synthesis of Azabicyclic Alkaloid Frameworks from Ketimine-Tethered Ynones: Total Synthesis of Indolizidine 209D

H. E. Ho, M. J. James, P. O'Brien, R. J. K. Taylor*, W. P. Unsworth*

9. Increasing Catalyst Efficiency in C–H Activation Catalysis

T. Gensch, M. J. James, T. Dalton, F. Glorius*

8. Deaminative Strategy for the Visible-Light-Mediated Generation of Alkyl Radicals

F. J. R. Klauck^†, M. J. James^†, F. Glorius*

7. Catalytic Dearomatization Approach to Quinolizidine Alkaloids: Five Step Total Synthesis of (±)-Lasubine II

M. J. James, N. D. Grant, P. O'Brien, R. J. K. Taylor*, W. P. Unsworth*

6. Silica-Supported Silver Nitrate as a Highly Active Dearomatizing Spirocyclization Catalyst: Synergistic Alkyne Activation by Silver Nanoparticles and Silica

A. Clarke, M. J. James, P. O'Brien, R. J. K. Taylor*, W. P. Unsworth*

5. Selective Synthesis of Six Products from a Single Indolyl α-Diazocarbonyl Precursor

M. J. James, P. O'Brien, R. J. K. Taylor*, W. P. Unsworth*

4. Catalyst-Driven Scaffold Diversity: Selective Synthesis of Spirocycles, Carbazoles and Quinolines from Indolyl Ynones

J. T. R. Liddon, M. J. James, A. K. Clarke, P. O'Brien, R. J. K. Taylor*, W. P. Unsworth*

3. Synthesis of Spirocyclic Indolenines

M. J. James, P. O'Brien, R. J. K. Taylor, W. P. Unsworth*

2. Silver(I)-Catalyzed Dearomatization of Alkyne-Tethered Indoles: Divergent Synthesis of Spirocyclic Indolenines and Carbazoles

M. J. James, R. E. Clubley, K. Y. Palate, T. J. Procter, A. C. Wyton, P. O'Brien, R. J. K. Taylor*, W. P. Unsworth*

1. Silver(I)- or Copper(II)-Mediated Dearom­atization of Aromatic Ynones: Direct Access to Spirocyclic Scaffolds

M. J. James, J. D. Cuthbertson, P. O'Brien, R. J. K. Taylor*, W. P. Unsworth*