Manchester Applied Mathematics and Numerical Analysis Seminars

Spring 2000

March 22, 2000, 4.00 pm

Lecture Theatre OF/B9 Oddfellows Hall (Material Science)


Molecular Pom-poms: The flow of branched polymer melts

Dr. Oliver Harlen, Dept. of Applied Mathematics, University of Leeds

Molten polymers have highly viscoelastic flow properties resulting from interactions between the highly flexible macromolecules that make up the fluid. A critical factor in determining the flow behaviour is the degree of branching within the molecular chain. For example two different polyethylenes with the similar molecular weights, but different branching structures, behave very differently when forced into a sudden contraction. In this seminar I will discuss a constitutive model for a melt of simple branched molecules, "pom-poms", that attempts to capture the underlying physics at the molecular level, but is still simple enough to be incorporated into a CFD code.

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For further info contact either Matthias Heil (mheil@ma.man.ac.uk), Mark Muldoon (M.Muldoon@umist.ac.uk)or the seminar secretary (Tel. 0161 275 5800).


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